X Close
Untitled Document
Brilliant, I personally admire the magazine and should become popular amongst all concerned in this field..

Dr G Sundararajan
Director , ARCI
Read more...  
Workshop on Electron Microscopy (WEM 2014)
International Conference on Advanced Nanomaterials and Emerging Engineering Technologies (ICANMEET-2
Thermoelectricity: From Atoms to Systems
Nanotech China
nano tech 2013 - The12th International Nanotechnology Exhibition & Conference
More events...
Untitled Document
`Hot` electrons
Wed, 10 May 2017
If they`re quick about it, "hot" electrons excited in a plasmonic metal can tunnel their way across a nanoscale gap to a neighboring metal. Rice University scientists said the cool part is what happens in the gap.

A Rice team discovered those electrons can create a photovoltage about a thousand times larger than what is seen if there is no gap. The finding shows it should be possible to create nanoscale photodetectors that convert light into electricity and can be used as sensors or in other sophisticated electronics.

Results from the Rice lab of condensed matter physicist Douglas Natelson appear in the American Chemical Society`s Journal of Physical Chemistry Letters.

Natelson`s lab studies the electronic, magnetic and optical properties of nanoscale structures, often by testing the properties of systems that can only be viewed under a microscope.

Some studies involve whole gold nanowires, and sometimes the lab breaks the wire to form a gap of just a few nanometers (billionths of a meter). One goal is to understand whether and how electrons leap the nanogap under various conditions, like ultracold temperatures.

While looking at such structures, the researchers found themselves studying the nanoscale characteristics of what`s known as the Seebeck (thermoelectric) effect, discovered in 1821, in which heat is converted to electricity at the junction of two wires of different metals. Seebeck discovered that a voltage would form across a single conductor when one part is hotter than the other.

"If you want to make thermostats for your house or your car climate control, this is how you do it," Natelson said. "You join together two dissimilar metals to make a thermocouple, and stick that junction where you want to measure the temperature. Knowing the difference between the Seebeck coefficients of the metals and measuring the voltage across the thermocouple, you can work backward from that to get the temperature."

To see how it works in a single metal on the nanoscale, Natelson, lead author and former postdoctoral researcher Pavlo Zolotavin and graduate student Charlotte Evans used a laser to induce a temperature gradient across a bowtie-shaped gold nanowire. That created a small voltage, consistent with the Seebeck effect. But with a nanogap splitting the wire, "the data made clear that a different physical mechanism is at work," they wrote.

Gold is a plasmonic metal, one of a class of metals that can respond to energy input from a laser or other source by exciting plasmons on their surfaces. Plasmon excitations are the back-and-forth sloshing of electrons in the metal, like water in a basin.

This is useful, Natelson explained, because oscillating plasmons can be detected. Depending on the metal and its size and shape, these plasmons may only show up when prompted by light at a particular wavelength.

In the bowties, laser light absorbed by the plasmons created hot electrons that eventually transferred their energy to the atoms in the metal, vibrating them as well. That energy is dissipated as heat. In continuous, solid wires, the temperature difference caused by the laser also created small voltages. But when nanogaps were present, the hot electrons passed through the void and created much larger voltages before dispersing.

"It`s a neat result," Natelson said. "The main points are, first, that we can tune the thermoelectric properties of metals by structuring them on small scales, so that we can make thermocouples out of one material. Second, a focused laser can act as a scannable, local heat source, letting us map out those effects. Shining light on the structure produces a small photovoltage.

"And third, in structures with truly nanoscale tunneling gaps (1-2 nanometers), the photovoltage can be a thousand times larger, because the tunneling process effectively uses some of the high-energy electrons before their energy is lost to heat," he said. "This has potential for photodetector technologies and shows the potential that can be realized if we can use hot electrons before they have a chance to lose their energy."

Gold seems to be the best metal to show the effect so far, Natelson said, as control experiments with gold-palladium and nickel nanogapped wires did not perform as well.

The researchers acknowledge several possible reasons for the dramatic effect, but they strongly suspect tunneling by the photo-generated hot carriers is responsible.

"You don`t need plasmons for this effect, because any absorption, at least in a short time, is going to generate these hot carriers," However, if you`ve got plasmons, they effectively increase the absorption. They interact with light very strongly, and the effect gets bigger because the plasmons make the absorption bigger."

Courtesy: ScienceDaily

Other News
Water forms `Spine of Hydration` around DNA
Mass-Producible Quantum Computers
Nanoscale Examination of a Living Cell Membrane
Insulating Nanomagnets Driven by Spin Torque
Water is surprisingly ordered on the nanoscale
Math, Biology and Nanotechnology
Energy Decay in Graphene Resonators
First flat lens for immersion microscopy
Oddball Enzyme to Build new Biomaterials out of DNA
Self-healing Battery Anodes
Nano Fiber feels forces, hears sounds
First `Nanotherapeutics` Drug Delivered to a Tumor
Precision Control using Magnetic Molecules
Anticancer Nanomaterials
New Computer Chips
Stretchable Hologram
Beautiful, Consistent Carbon Belts
Nanoscale Imaging
Subatomic Scale
Wood filter
More Wfficient Catalytic Material Developed
New material changes to the environment
Record Resolution at a nanometer length scale
Exotic nanomaterials
Nanoparticles explaining risks to heart
Nanodiamond-enhanced MRI
Single-molecule diode created
A novel form of iron for fortification of foods
Bonding Chips using Inkjet Printers
Nanoparticles helps Melanoma Treatment
Imaging at the Speed of Light
Reusable Sponge that Soaks up Oil
Color-Changing Glass
Molecular `Leaf`
Optical Metamaterial
Most Complex nanoparticles Designed
Low-Cost Diagnostic Systems
Ultralight Web of Silk Nano Fibers
shape-Shifting Molecular Robots
Magnetic `Persuasion` in Neighboring Metals
Anti-Fogging Water-Repellent Nanotextures
Portable Nanofiber
Resilient Flight Computers
Triboelectric nanogenerators
Nano `sandwich`
Computing with Biochemical Circuits made Easy
  Untitled Document
  Untitled Document
Untitled Document
  Follow us On  Follow us on FacebookFollow us on Twitter  
© 2010 Nano Digest. All Rights Reserved.   - Rify Hosting -